First note that there is a difference between the dash, - , used as the subtraction operator and as the negative sign. Though we use the same character, they have a different meaning.
Both positive and negative integers, like -4, take only a single slot in the stack.
If your postifx language can only take single-digit integers and the arithmetic operators, you can represent negative numbers by subtracting from zero:
04-2+
This is equivalent in infix notation to
0-4+2
Here is some terminology: the subtraction operation is a "binary operator," that is, it takes two operands; the negative sign is a "unary operator," that is, it takes one operand. Infix and postfix are notations for binary operators and their operands.