Generally I am strongly in favor of not restricting what kinds of characters are allowed in passwords. However, remember that you have to compare something to something stored which may be the password or a hash. In the former case you have to make sure that comparison is done correctly which is much more complex with Unicode than with ASCII alone; in the latter case you would have to ensure that you are hashing exactly the same whenever it is entered. Normalization forms may help here or be a curse, depending on who applies them.
For example, in an application I m working on I am using a hash over a UTF-8 conversion of the password which was normalized beforehand to weed out potential problems with combining characters and such.
The biggest problem the user may face is that they can t enter it in some places, like on another keyboard layout. This is already the case for one of my passwords but never was a problem so far. And after all, that s a decision the user has to make in choosing their password and not one the application should make on behalf of the user. I doubt there are users who happily use arbitrary Unicode in their passwords and not think of the problems that may arise when using another keyboard layout. (This may be an issue for web-based services more than anything else, though.)
There are instances where Unicode is rightly forbidden, though. One such example is TrueCrypt which forces the use of the US keyboard layout for boot-time passwords (for full-volume encryption). There is no other layout there and therefore Unicode or any other keyboard layout only produces problems.
However, that doesn t explain why they forbid Unicode in normal passwords. A warning might be nice but outright forbidding is wrong in my eyes.