IIS only supports kerberos for NTLM authentication as far as I know. I have never seen a secondary kerberos capable library or software. (true kerberos I mean) Now you could use the LDAP libraries in .Net to communicate between the servers in a kerberos fashion, but the connection between user client and asp.net server would still be an SSL plain/text connection.
I ve also never seen it done, but it should be able to be done ... if the asp.net server had a trust relationship with the Apple Open Directory server with an LDAP connection made between the two, it might be possible to enable the NTLM authentication at the IIS level, and that would (in theory) extend the kerberos connectivity to the AOD through the trust. Again, I ve never even contemplated it so I don t know what the pitfalls would be of attempting it.
I have successfully used DirectoryServices to connect to other Active Directories through the LDAP protocol, but I still have not found a way to embed the kerberos connectivity between client and authentication server without NTLM.